Evaluation of Sensing Efficiency of Selected Organic Acids Derivatives toward Metal Ions in Aqueous Medium
| Author | AL-Zaimoor, Eman Faisal Hasan | |
|---|---|---|
| metadata.dc.contributor.department | University of Bahrain, College of Science, Department Biochemistry | |
| metadata.dc.date.accessioned | 2026-09-20T15:47:50Z | |
| Publication date | 2024 | |
| Degree level | Master | |
| Abstract | Abstract : Non-covalent organic heterosynthons show enhanced properties in contrast to their individual coformers, rendering them promising for various applications. Specifically, hydrogen-bonded heterosynthons have shown effective coordination behavior with diverse metal ions, hinting at their potential for rapid optical sensing. Their straightforward synthesis and the interactions between the coformers make them good candidates for detection purposes. In this study, five hydrogen-bonded heterosynthons, phthalic-2-amino-3-methylpyridine 1, phthalic-imidazole 2, dipicolinic acid-pyrazole 3, dipicolinic acid-imidazole 4, and dipicolinic acid-2-amino-3-methylpyridine 5, of two distinct dicarboxylic acids were synthesized using slow evaporation method and characterized using FTIR, UV-Vis, 1H-NMR, and PXRD spectroscopic techniques. Physical mixtures with different molar ratios, using the same coformers were prepared through a grinding method. Binary phase diagrams were constructed, and FTIR analysis was performed to propose the type of heterosynthons being formed. The colorimetric detection efficiency of the synthesized heterosynthons towards a wide range of metal ions was examined and compared to that of their individual acids. Interestingly, all heterosynthons demonstrated enhanced colorimetric sensing performance towards metal ions. However, dipicolinic acid-pyrazole 3 and dipicolinic acid-2-amino-3-methylpyridine 5, did not show any significant color change in the presence of Ni(II) in contrast to their pure acid. This could be enhanced by improving the structural conjugation of the prepared heterosynthons and accordingly intensifying the obtained color and enhancing the naked-eye colorimetric detection results | |
| metadata.dc.identifier.other | Drupal node 3405 | |
| metadata.dc.identifier.other | https://digitalrepository.uob.edu.bh/en/dar/evaluation-sensing-efficiency-selected-organic-acids-derivatives-toward-metal-ions-aqueous | |
| metadata.dc.identifier.uri | http://165.227.56.122/handle/123456789/6644 | |
| Language | en | |
| Link | https://digitalrepository.uob.edu.bh/en/_flysystem/fedora/2025-05/2025_evaluation_of_sensing_efficiency_of_selected_organic_acids_derivatives_toward_metal_ions_in_aqueous.pdf | |
| Title | Evaluation of Sensing Efficiency of Selected Organic Acids Derivatives toward Metal Ions in Aqueous Medium | |
| Type | Master's Thesis |
Files
Original bundle
1 - 1 of 1
Loading...
- Name:
- node-3405-1-2025_evaluation_of_sensing_efficiency_of_selected_organic_acids_derivatives_toward_metal_ions_in_aqueous.pdf
- Size:
- 4.52 MB
- Format:
- Adobe Portable Document Format